There are four primary considerations in elastomer selection:
temperature, chemical compatibility, physical attributes
(including abrasion and tear resistance) and cost. The first
step in selecting the proper elastomer is determining which
polymer family best suits the application. The following
is an outline of physical and chemical characteristics pertaining
to deVries International’s nine most commonly used
polymers.
In determining the correct polymer family for your application,
the first consideration should be the system’s operating
temperature. If the upper limit of the temperature range is
exceeded, a chemical reaction within the elastomer will cause
it to change permanently, resulting in loss of elastic properties
needed for effective sealing. Temperatures below the lower
limit of the elastomer cause only a non-permanent hardening.
As the elastomer warms back within its temperature limits
all of its original properties will return.
A seal’s compatibility with the fluid to be sealed
is determined by the elastomer’s stability while immersed
in that fluid. Changes in the elastomer’s hardness,
tensile, elongation, and volume are measured after immersion
in the fluid with the smallest changes in these properties
identifying the most suitable seal material. A “1”
rating reflects maximum stability while a “3”
rating shows the greatest physical change and a material
not recommended for use in that fluid. (See Fluid
Compatibility Chart.) The outline of polymer families
below will also provide an indication of physical
strength as well as relative costs.
Position cursor over
elastomer below for description.
Nitrile or
Buna-N is a co-polymer of butadiene and acrylonitrile. Acrylonitrile
content determines the elastomer’s resistance to petroleum
based oils and hydrocarbon fuels. Increasing the acrylonitrile
percentage improves the resistance to these fluids, but reduces
low temperature flexibility. Other additives can be incorporated
into Nitrile to improve low temperature flexibility. With a temperature
range –65° to 225°F in oil seal applications, Nitriles exhibit
excellent compression set, tear and abrasion resistance. They do
not possess good resistance to sunlight, ozone, and outdoor weathering.
This material is the most widely used and cost effective oil seal
elastomer. Nitrile is considered the cost datum for this section;
other elastomers will reflect cost comparisons to Nitrile oil seals.
Neoprenes are
homopolymers of chlorobutadiene with service temperatures from –65°
to 300°F. This material is unique in its limited resistance to
petroleum products, ozone and weathering, and relatively low cost.
Neoprene typically has a 20% premium over the cost of Nitrile oil
seals.
Polyacrylate is
a co-polymer of ethyl and butyl acrylates. This material has
excellent resistance to petroleum products, ozone and sunlight.
Its continuous temperature range is between –40° and 300°F
when used in oil seals. Polyacrylates have been commonly used in
automotive transmissions, transfer cases and power steering units.
Higher performance demands of modern car designs have replaced
Polyacrylate with higher performance materials such as Fluoroelastomers,
HNBR and Vamac. Polyacrylate has 30% premium over Nitrile oil seals.
Ethylene
propylene is a terpolymer made up of ethylene, propylene and a
diene monomer. These materials are used in sealing automotive brake
fluids, water, steam and fire resistant hydraulic fluids. They
are not recommended for use in petroleum based fluids or di-ester
lubricants.
Ethylene Propylene can be processed with two different curing systems:
peroxide, EP, with a temperature range of –65° to 300°F and
excellent compression set resistance; or sulfur, ES, which handles
temperatures from –65° to 212°F and average compression set
resistance. Both materials exhibit similar chemical resistance.
The ES compounds have a 20% premium over nitrile while the EP materials
have a 40% premium.
Vamac polymer,
produced by E.I. duPont, is a terpolymer of ethylene, methyl
acrylate and carboxylic monomers. Vamac’s operational
temperature range is between –30° and 350°F. It has excellent
resistance to ozone, weathering, water, mineral oils, acid, and
good resistance to petroleum oils and transmission fluid. Vamac
has a 40% premium over nitrile oil seals.
Fluoroelastomer,
commonly known by its E.I. duPont trade name, Viton, is chemically
described as a co-polymer of Vinylidene fluoride and Hexafluoropropylene.
This material has comparable strength and wear resistance to Nitrile,
but exhibits exceptional temperature and chemical resistance with
service limits for oil seals from –40° to 400°F. It has been
commonly used as a high performance replacement for Nitrile and
Polyacrylate. Fluoroelastomers exhibit the widest range of chemical
resistance, including petroleum products, water, ozone, di-esters
and acid resistance. It is priced at a 300% premium over Nitrile
oil seals.
By varying fluorine content, Fluoroelastomers can be designed to
handle more aggressive applications. Increasing the fluorine level
in the base polymer creates improved fluid resistance but decreases
low temperature flexibility. For these applications, where both
low temperature and high chemical resistance are required, adding
a cure site monomer and peroxide cure system to the high fluorine
base polymer produces the best results.
Silicone elastomers
are produced from silicone, oxygen, hydrogen and carbon and carry
a chemical name of Polydimethylsiloxane. Silicone has
exceptional dry temperature resistance, being able to handle –80°
to 450°F. Silicone possesses excellent resistance to weathering,
sunlight and ozone. It is recommended for use in convoluted boots
where weathering and flex life are critical. Silicone is normally
considered to be a low tensile and tear strength material with
marginal resistance to petroleum based products. However, deVries
International has developed a high strength, petroleum based grease
and oil resistant Silicone which is widely used in heavy duty,
air disc brake applications where weathering, abrasion and petroleum
resistance are critical. Silicone typically carries an 80% premium
over Nitrile oil seals.
Teflon is
chemically known as Polytetrafluoroethylene which is a fluorocarbon
plastic with a temperature range from –120° to 500°F. It
is chemically resistant to virtually all fluids and exhibits excellent
dry running properties. As a plastic, this material lacks the elastic
resilience of synthetic rubber sealing materials. Teflon is very
notch or cut sensitive during seal installation and requires very
careful handling. It can become an excellent oil seal component
when used in conjunction with other elastomers that will make up
for its shortcomings in resilience. A combination of HNBR and reinforced
teflon has become an industry standard in automotive air-conditioning
compressor shaft seals. Due to the customized nature of teflon
shaft seal designs there is not a direct cost correlation to Nitrile
oil seals.
Hydrogenated
Nitrile is a co-polymer of butadiene and acrylonitrile
that has been saturated with hydrogen. This is an exceptional material
exhibiting
tensile strength 50% greater than that of Nitrile and other high
strength elastomers. Its temperature range for oil seals is –50°
to 300°F. HNBR has excellent tear strength, compression set and
chemical resistance to petroleum products, a wide range of solvents,
weathering and ozone. It also provides superior steam resistance.
HNBR has a 120% premium over Nitrile oil seals.